Thermostabilizer for Polyvinyl Chloride-development of Synergistic Compounds

Authors

  • S.Sh. Lutfullaev Associate Professor, Karshi Engineering-Economics Institute
  • Sh.X. Tavashov Associate Professor, Karshi Engineering-Economics Institute
  • M.F. Dostmuradova Assistant, Karshi Engineering-Economics Institute

DOI:

https://doi.org/10.47134/jme.v1i2.2651

Keywords:

Stabilizers, Calcium, Barium and Lead Salts, Polymer and Polymer Decomposition Products, Strong Inhibitors, Synthesized Stabilizer, Polymer Compositions

Abstract

Thermostabilizer-synergistic mixtures with double salts of T-product for PVX were developed and their synergism efficiency phenomena were studied using DTA and TGA methods. The mixtures of thermostabilizers synergics of mixed salts of the product – T for PVCh were worked out by the methods of DTA and TGA and the effect of synergism was studied. This study aims to develop thermostabilizer-synergistic mixtures with double salts of T-product for polyvinyl chloride (PVC) and to investigate their synergistic efficiency using Differential Thermal Analysis (DTA) and Thermogravimetric Analysis (TGA) methods. The research involved synthesizing stabilizers, preparing PVC mixtures, conducting heat resistance tests, and analyzing the data obtained. The efficiency of the synergistic mixtures was evaluated through DTA and TGA to assess their impact on the thermal stability and degradation behavior of PVC. The study found that the synergistic mixtures significantly enhanced the thermal stability of PVC. The results indicated that the mixtures, particularly those involving lead salts of T-product, demonstrated a pronounced synergistic effect, delaying the onset of thermal degradation and improving overall stability. The effectiveness of the stabilizers was 2-3 times higher when used in mixtures compared to individual use. The optimal ratio for maximum stabilization efficiency was found to be 1:1, with specific mixtures showing an induction period of up to 120 minutes. The developed thermostabilizer-synergistic mixtures with double salts of T-product effectively enhance the thermal stability of PVC. The synergistic interactions between the components contribute to improved performance, making these mixtures promising candidates for enhancing the durability and lifespan of PVC materials. This advancement addresses critical issues related to environmental sustainability, performance enhancement, cost reduction, and market expansion, ensuring that PVC remains a viable and valuable material for a wide range of applications.

References

Abdelnabi, R. (2017). Glutathione is a highly efficient thermostabilizer of poliovirus Sabin strains. Vaccine, 35(10), 1370–1372. https://doi.org/10.1016/j.vaccine.2017.01.070 DOI: https://doi.org/10.1016/j.vaccine.2017.01.070

Aghamaliyev, Z. Z. (2018). Synthesis of 2-hydroxy-3-(methylcyclohexenyl-isopropyl)-5-methylbenzylaminoethylnonyl imidazolines-the thermostabilizers to polypropylene. Materials Science Forum, 935, 155–159. https://doi.org/10.4028/www.scientific.net/MSF.935.155 DOI: https://doi.org/10.4028/www.scientific.net/MSF.935.155

Aisawa, S. (2019). Preparation of dipentaerythritol-combined layered double hydroxide particle and its thermostabilizing effect for polyvinyl chloride. Applied Clay Science, 180. https://doi.org/10.1016/j.clay.2019.105205 DOI: https://doi.org/10.1016/j.clay.2019.105205

Akcapinar, G. B. (2015). Modulating the thermostability of Endoglucanase I from trichoderma reesei using computational approaches. Protein Engineering, Design and Selection, 28(5), 127–135. https://doi.org/10.1093/protein/gzv012 DOI: https://doi.org/10.1093/protein/gzv012

Aripov, E. A., Pyak, L. K., Khamidov, B. N., Mergenbaeva, H. U., & Abduvaliev, N. A. (1994). Plastic, Stabilizing and Filled PVC Composite. Science.

Castro, E. De. (2016). Direct determination of sorbitol and sodium glutamate by attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR) in the thermostabilizer employed in the production of yellow-fever vaccine. Talanta, 152, 33–38. https://doi.org/10.1016/j.talanta.2016.01.054 DOI: https://doi.org/10.1016/j.talanta.2016.01.054

Chirikov-Zorin, I. (2014). The design of a module of a new electromagnetic calorimeter for COMPASS II. Physics of Particles and Nuclei Letters, 11(3), 252–258. https://doi.org/10.1134/S1547477114030066 DOI: https://doi.org/10.1134/S1547477114030066

Gorelik, Y. B. (2016). About efficiency of the condenser finning of the short vertical thermostabilizer for building on permafrost. Earth’s Cryosphere, 20(2), 78–89.

Hwang, J. H. (2020). Three-percent sucrose acts as a thermostabilizer for cell-adapted foot-and-mouth disease virus without any negative effect on viral growth. Journal of Applied Microbiology, 128(5), 1524–1531. https://doi.org/10.1111/jam.14565 DOI: https://doi.org/10.1111/jam.14565

Komarov, I. A. (2015). Problem of utilization of the cooling capacity of natural liquid gas for the termostabilization of ground. Earth’s Cryosphere, 19(2), 75–80.

Kuzma-Kichta, Y. A. (2020). Investigation of the effect of nanoparticle coatings on the transport properties of a thermostabilizer evaporator. Journal of Physics: Conference Series, 1683(2). https://doi.org/10.1088/1742-6596/1683/2/022079 DOI: https://doi.org/10.1088/1742-6596/1683/2/022079

Lavrikov, A. V. (2017). Investigation of heat transfer enhancement and thermal resistance of weakly inclined thermostabilizer. Journal of Physics: Conference Series, 891(1). https://doi.org/10.1088/1742-6596/891/1/012150 DOI: https://doi.org/10.1088/1742-6596/891/1/012150

Maksimenko, V. (2018). Using thermostabilizers in industrial refrigeration units with circulating water supply system schemes. AIP Conference Proceedings, 2007. https://doi.org/10.1063/1.5051877 DOI: https://doi.org/10.1063/1.5051877

Maximenko, V. A. (2018). Development of design and methods for soil directional thermostabilizer simulation. AIP Conference Proceedings, 2007. https://doi.org/10.1063/1.5051921 DOI: https://doi.org/10.1063/1.5051921

Maximenko, V. A. (2019). The algorithm for calculating a ground thermostabilizer development in an ansys environment. AIP Conference Proceedings, 2141. https://doi.org/10.1063/1.5122083 DOI: https://doi.org/10.1063/1.5122083

Minsker, K. S., & Fedoseeva, G. T. (1979). Destruction and Stabilization of PVC. Chemistry.

Muhammed, M. (2019). Three dimensional structure prediction of panomycocin, a novel Exo-β-1,3-glucanase isolated from Wickerhamomyces anomalus NCYC 434 and the computational site-directed mutagenesis studies to enhance its thermal stability for therapeutic applications. Computational Biology and Chemistry, 80, 270–277. https://doi.org/10.1016/j.compbiolchem.2019.04.006 DOI: https://doi.org/10.1016/j.compbiolchem.2019.04.006

Pasche, A. (2017). Zr-doped TiO2 as a thermostabilizer in plasmon-enhanced dye-sensitized solar cells. Journal of Photonics for Energy, 7(3). https://doi.org/10.1117/1.JPE.7.035504 DOI: https://doi.org/10.1117/1.JPE.7.035504

Pathak, A. (2017). Water isotope effect on the thermostability of a polio viral RNA hairpin: A metadynamics study. Journal of Chemical Physics, 146(16). https://doi.org/10.1063/1.4982049 DOI: https://doi.org/10.1063/1.4982049

Romano, A. (2021). An Empirical Study of Bugs in WebAssembly Compilers. Proceedings - 2021 36th IEEE/ACM International Conference on Automated Software Engineering, ASE 2021, 42–54. https://doi.org/10.1109/ASE51524.2021.9678776 DOI: https://doi.org/10.1109/ASE51524.2021.9678776

Ruzieva, Z. T., & Dustmurodova, M. F. (2022). Investigation of the Solubility of the Ternary System KCl – K2SO4 – H2O. International Journal on Orange Technology, 46–48. https://journals.researchparks.org/index.php/IJOT/article/view/2996

Ruzieva, Z. T., & Dustmurodova, M. F. (2023a). Development Receiving Nitrogen Salts. Central Asian Journal of Theoretical and Applied Sciences, 4(12), 1–7. https://cajotas.centralasianstudies.org

Ruzieva, Z. T., & Dustmurodova, M. F. (2023b). Obtaining Potassium Sulfate by Conversion of Sylvite With Mirabilite. International Journal of Formal Education, 2(3). http://journals.academiczone.net/index.php/ijfe/article/view/604

Ruzieva, Z. T., & Dustmurodova, M. F. (2023c). Physico-Chemical Fundamentals Preparation of Potassium Sulfate from Potassium Chloride and Mirabilite. International Journal. Miasto Przyszłości, 33, 63–66. https://miastoprzyszlosci.com.pl/index.php/mp/article/view/1186

Shabaev, A. S. (2019). Study of Thermo-Oxidative Transformations of Unstabilized and Stabilized Poly(ether ether ketone). Polymer Science - Series B, 61(5), 582–588. https://doi.org/10.1134/S1560090419050154 DOI: https://doi.org/10.1134/S1560090419050154

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Published

2024-06-06

How to Cite

Lutfullaev, S., Tavashov, S., & Dostmuradova, M. (2024). Thermostabilizer for Polyvinyl Chloride-development of Synergistic Compounds. Journal of Mechanical Engineering, 1(2), 7. https://doi.org/10.47134/jme.v1i2.2651

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